欧洲杯开赛后最重大的小组出身。E组第二轮比赛中，乌克兰对阵斯洛伐克。

斯洛伐克首轮打败小组种子队比利时树立本届欧洲杯第一个大冷门，此番如故面临排行比我方高的敌手，第17分钟起首破门。哈拉斯林底线处传中，津琴科门前造作冒顶，施兰茨头球破门，1比0提高。

乌克兰首轮惨败给罗马尼亚，此番已退无可退。下半场，球队终于醒悟。第54分钟，津琴科助攻沙帕伦科破门，乌克兰打入本届欧洲杯首球，1比1追平比分。

之后两边齐有念念法拿下敌手，最终如故乌克兰把捏住了契机。第80分钟，沙帕伦科助攻，替补出场的亚列姆丘克轻巧停球后，丝滑连合射门攻破敌手大门，乌克兰2比1反超，拿下3分。这么一来，唯有天下第三比利时如故在E组莫得积分，其他3队齐得回3分，全乱了。

本轮比利时对阵罗马尼亚，要是比利时取胜，将出现4队3分的情况。

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